全球知識產權大型服務機（jī）構
10年專注全球（qiú）知識產權（quán）服務
- 全國24小時（shí）熱線：
- 400-1688-019
10年專注全球（qiú）知識產權（quán）服務
當前位置：首頁>政策&谘詢>91成人影院新聞（wén）
2019年10月9日，瑞典皇家科學院將2019年（nián）諾貝爾化學獎授予美國的（de）John B. Goodenough、英國的Stanley Whittingham以及日本的Akira Yoshino，以表（biǎo）彰他們在鋰離子（zǐ）電池研究方麵（miàn）的突（tū）出貢獻。
2019年的諾貝爾化學獎實至名歸，鋰離子電池對現代社會的影響深遠，從移動電子到電動汽車都廣泛應用。
但是鋰離（lí）子電（diàn）池（chí）的研究道路卻充滿了波折，這裏麵摻（chān）雜著專利戰（zhàn）、商業間諜、技術產業化競爭（zhēng）等複雜的故事情節。
最先（xiān）做出鋰離子（zǐ）電池的是英國的（de）Stanley Whittingham，他在（zài）上世紀70年（nián）代開始申請了鋰離（lí）子電（diàn）池（chí）方麵的（de）一係列專利。
US-4007055-A | Preparation of stoichiometric titanium disulfide |
US-4040917-A | Preparation of intercalated chalcogenides |
US-4009052-A | Chalcogenide battery |
US-4049879-A | Intercalated transition metal phosphorus trisulfides |
US-4049887-A | Electrochemical cells with cathode-active materials of layered compounds |
CA-1094777-A | Preparation of stoichiometric titanium disulfide |
US-4086403-A | Alkali metal/niobium triselenide cell having a dioxolane-based electrolyte |
CA-1036535-A | Preparation of intercalated chalcogenides |
US-4143213-A | Cells having cathodes containing chalcogenide compounds of the formula Ma FeXb and species thereof exhibiting alkali metal incorporation |
US-4139682-A | Cells having cathodes derived from ammonium-copper-molybdenum-chalcogen compounds |
US-4144384-A | Cells having cathodes with vanadium-chalcogen-containing compounds |
US-4166160-A | Cells having cathodes derived from ammonium-molybdenum-chalcogen compounds |
US-4201839-A | Cell containing an alkali metal anode, a solid cathode, and a closoborane and/or closocarborane electrolyte |
US-4243624-A | Method of making cathodes derived from ammonium-metal-chalcogen compounds |
US-4233375-A | High energy density plural chalcogenide cathode-containing cell |
CA-1099333-A | Electro chemical cell with titanium disulfide cathode |
US-4339424-A | Method of preparing W or Mo metal oxides |
US-5514490-A | Secondary lithium battery using a new layered anode material |
US-2016365577-A1 | Vanadyl phosphates as high energy density cathode materials for rechargeable sodium battery |
US-2017373310-A1 | Kvopo4 cathode for sodium ion batteries |
US-2019273257-A1 | Epsilon-VOPO4 CATHODE FOR LITHIUM ION BATTERIES |
Stanley Whittingham的專利
從（cóng）70年代開始，Stanley Whittingham在鋰離子領域申請（qǐng）了幾十件專利，最（zuì）近的一件專利（lì）申請還是在（zài）2019年公開的，可見其對鋰離子電池研究的激情。
但（dàn）是可惜的是，Stanley Whittingham最初的鋰離子電池存在諸多問題，無法商業化。
在Stanley Whittingham的基礎上，當時還在（zài）牛津大學工作的美國科學家Goodenough發現了一種更好的材料氧化鈷鋰，這一發（fā）現直接促使了日（rì）本企業將鋰電（diàn）池正式商業化。但離奇的是，當時的牛津（jīn）大學竟然未對該成果申請專利。日本企業相當於白白（bái）使用了這一成果。Goodenough一直在幾十年後還對牛津（jīn）大學的決定懊惱不已。牛津大學的這一決定損失（shī）了至少幾億美元（yuán）的專利（lì）許可費。此後，Goodenough在（zài）鋰電池領域不斷改進，最終發明了磷酸鐵鋰電池，這也是如今電（diàn）動汽車領（lǐng）域使用最普遍的電池。但這一次Goodenough又在（zài）專利上跌了跟頭，日本電訊公司（sī）將一名（míng）員工Osada送到他的實驗室當訪問研究員，Goodenough後來在法庭上說他是出於友誼答應的，沒想到回到日本後Osada偷偷地將相關技術申請了（le）專利，導致Goodenough大為惱火，在美國起訴日本企業竊取知識產權，索賠（péi）5億美元。但是在訴訟進行（háng）的過程中，日本企業（yè）在鋰電（diàn）池方麵早已實現了騰飛（fēi）。
Goodenough一直90多歲還（hái）在做（zuò）研究，最近（jìn）的一件專利是（shì）在2018年公（gōng）開了，95歲還在申請專利。他（tā）在鋰（lǐ）電池方麵申請過20多個專利，當然最關鍵（jiàn）的發明都沒有得到多很好的保護，否則（zé）Goodenough早已是億萬（wàn）富豪了。
US-4049891-A | Compositions for fast alkali-metal-ion transport |
US-4302518-A | Electrochemical cell with new fast ion conductors |
US-4507371-A | Solid state cell wherein an anode, solid electrolyte and cathode each comprise a cubic-close-packed framework structure |
US-5910382-A | Cathode materials for secondary (rechargeable) lithium batteries |
DE-6020470-T1 | Cathode material for secondary (rechargeable) lithium batteries |
US-6514640-B1 | Cathode materials for secondary (rechargeable) lithium batteries |
US-6221812-B1 | Jc in high magnetic field of bi-layer and multi-layer structures for high temperature superconductive materials |
WO-2006130766-A2 | Cathodes for rechargeable lithium-ion batteries |
US-2012052401-A1 | Niobium Oxide Compositions and Methods for Using Same |
US-2014080019-A1 | MONOCLINIC Sr1-xAxSi1-yGeyO3-0.5x, WHEREIN A IS K or Na, OXIDE ION CONDUCTOR |
US-2015050578-A1 | Oxide-ion conductors and related composites and devices |
US-2016351904-A1 | Cathode additive for rechargeable lithium batteries |
US-9890048-B2 | Water solvated glass/amorphous solid ionic conductors |
US-2017005327-A1 | Cathode additive for rechargeable sodium batteries |
US-10236513-B2 | Alkali-metal batteries with a dendrite-free anode interfacing an organic liquid electrolyte |
US-2018287222-A1 | Self-charging and/or self-cycling electrochemical cells |
WO-2018013485-A1 | Self-charging and/or self-cycling electrochemical cells |
US-10381683-B2 | Metal plating-based electrical energy storage cell |
US-2019115162-A1 | Heat energy-powered electrochemical cells |
US-2018287150-A1 | Electrochemical cells with a high voltage cathode |
Goodenough的專利申請（qǐng）
但從知識產權保護方麵來說，來自日本的科學家Akira Yoshino是最成功的，他的技術直接推動了鋰電池的商業化。Akira Yoshino在鋰電池領（lǐng）域一共申請了（le）50多件專利，也為此獲得了巨大的商業利（lì）益。
US-4226908-A | Water repellent inorganic foam and method for producing the same |
US-4207113-A | Inorganic foam and preparation thereof |
CA-1103405-A | Inorganic foam and preparation thereof |
JP-S60127669-A | Secondary battery |
JP-S60127309-A | Stabilization of n type polyacetylene |
JP-S60127307-A | Electrochemical stabilization of n type polyacetylene |
JP-S60262351-A | Composite negative electrode of secondary battery |
US-4634636-A | Polyacetylene composite |
JP-S61285678-A | Electrochemical method for stabilizing n-type polyacetylene |
EP-0205856-B1 | Secondary battery |
JP-S633393-A | Card processing system with display function |
JP-H0422066-A | Nonaqueous secondary battery |
JP-H0574453-A | Organic secondary battery |
JP-H0574452-A | New secondary battery |
JP-H0574436-A | Separator for battery |
JP-H0574461-A | Secondary battery negative electrode |
JP-H0574442-A | Battery separator |
JP-H0574494-A | Nonaqueous secondary battery |
JP-H0574493-A | Secondary battery equipped with safety element |
JP-H0574455-A | Organic electrolyte battery |
JP-H0574485-A | Nonaqueous electrolyte secondary battery |
JP-H0585741-A | Method for firing multiple oxide |
JP-H0594822-A | Battery |
JP-H0620672-A | Separator for nonaqueous battery |
WO-9306628-A1 | Secondary cell |
JP-H06111805-A | Positive electrode pin for battery |
JP-H06111804-A | Resin sealed positive electrode terminal |
JP-H06111803-A | Positive electrode terminal for battery |
JP-H06111802-A | Positive electrode pin structure |
JP-H0750159-A | Battery with new rupture |
JP-H0750160-A | Positive electrode pin |
AU-655710-B2 | .econdary battery |
TW-211084-B | Secondary battery |
JP-H07176302-A | Secondary battery |
JP-H07176303-A | Manufacture of secondary battery electrode |
JP-H08106886-A | Batteries |
JP-H11176996-A | Coated electronic circuit |
JP-2001357724-A | Anti-corrosive overhead wire |
JP-2002020777-A | Grease and aerial power transmission line obtained by using the same |
JP-2004095338-A | Corrosion-protected wire |
JP-2004095337-A | Corrosion proof electric supply cable |
JP-2006324554-A | Fluorine-containing organic sulfonyl imido salt electrolyte, and electrolytic solution and electrochemical component using same |
JP-2006324167-A | Unsymmetrical organic sulfonylimide salt electrolyte, electrolyte solution and electrochemical element using the same |
CA-2662423-C | Polymer electrolyte comprising a ketonic carbonyl group and electrochemical device comprising said electrolyte |
EP-2063436-B1 | Polymeric electrolyte, method for production thereof, and electrochemical element |
JP-2009087875-A | High heat radiation electrochemical element and power supply device |
US-9893378-B2 | Non-aqueous electrolyte solution and non-aqueous secondary battery |
JP-2013199176-A | Liquid-gas transport vehicle |
JP-2015065050-A | Nonaqueous electrolytic solution, and nonaqueous secondary battery |
JP-2015072805-A | Nonaqueous secondary battery |
JP-2017152085-A | Nonaqueous electrolytic solution and nonaqueous secondary battery |
EP-3467930-A1 | Nonaqueous electrolyte and nonaqueous secondary battery |
EP-3279996-B1 | Nonaqueous electrolyte and nonaqueous secondary battery |
Akira Yoshino的鋰（lǐ）電池專利申請
2019年諾貝爾化學獎也反映了（le）各國的研發思（sī）路。歐美更注重原始的創新，日本的基礎研究更靠近產（chǎn）業實踐。日本企業在鋰電池的產業（yè）中獲得了最大的利益。
返回（huí）